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Tag: Ammonia Cracking

Ammonium salt formation conditions based on measured vapour pressures

ASRL has conducted studies on ammonia destruction in the sulphur recovery unit (SRU) for over a decade1-5 . Other studies at ASRL have investigated mechanisms for ammonium salt formation and deposition downstream in the Claus plant, as well as the potential sources of ammonia (NH3 )in a gas plant7 . A less understood subject is addressing how much residual NH3 is tolerable or at what temperature will residual NH3 cause ammonium salt deposition. In this study, existing knowledge on thermal stability of ammonium salts and new measurements have been used to identify the gaseous components required for deposition, through reversible vapour pressure expressions.