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Ammonium nitrate – still growing
In spite of continuing safety concerns due to the Beirut explosion, and the rise of the use of urea as a nitrogen fertilizer, ammonium nitrate demand continues to increase in several key markets.
In spite of continuing safety concerns due to the Beirut explosion, and the rise of the use of urea as a nitrogen fertilizer, ammonium nitrate demand continues to increase in several key markets.
With increasing frequency, companies that have molten sulphur on site must put environmental controls on the vent streams from molten sulphur pits, storage tanks and loading operations. This article* describes the typical characteristics of molten sulphur vent gas streams as well as some of the important chemistry related to these systems in caustic scrubbers. Solids deposition issues observed in the field with caustic scrubbers operating on actual molten sulphur vent gas streams are presented. Design and operational strategies to mitigate plugging in molten sulphur vent gas scrubbers are also summarised in this article by D. J. Sachde, K. E. McIntush, D. L. Mamrosh , and C. M. Beitler of Trimeric Corporation.
At the end of last year, in our November/ December 2019 issue, I remarked upon the fresh impetus that the International Maritime Organisation’s (IMO) target of reducing carbon emissions from shipping by 50% in 2050 (compared to a 2008 baseline) had given to the idea of using ammonia as a shipping fuel. This year, in spite of You Know What, things seem to have, if anything, accelerated.
High pressure urea equipment often has lined nozzles. A lined nozzle is a full strength carbon steel nozzle that is protected against carbamate corrosion by a 5 or 6 mm thick stainless steel liner plate, which is welded to the carbon steel nozzle on either end. This design is however very vulnerable to fatigue cracking due to the difference in thermal expansion between the austenite liner and the carbon steel nozzle. History shows that such a design will lead to cracking in the long term. The following case study reports on a serious incident in a urea plant where a leak in a urea reactor nozzle caused a plant shutdown but could have resulted in rupture of the high pressure vessel.
Maire Tecnimont subsidiary Tecnimont SpA has finalised its $350 million EPC contract with Egypt Hydrocarbon Corp. (EHC) for the construction of a new ammonia plant at Ain Sokhna. The preliminary contract was announced in September last year. The contract for the plant, which will produce 1,320 t/d of ammonia, also includes extensive utilities and offsite facilities. Project completion is scheduled for 36 months from the effective contract date, which will be triggered by financial closure of the project. Project finance is being arranged by the Italian export credit agency SACE and the US EXIM Bank. The ammonia will be used to feed an ammonium nitrate plant, already existing and in operation in the same industrial facility, also owned by EHC.
Air Products and Haldor Topsoe have signed a global alliance agreement. Under the terms of the agreement the two companies will use their combined market network for developing potential projects and the combination of their expertise on large-scale ammonia, methanol and/or dimethyl ether (DME) plants to be developed and built globally. It gives Air Products access to Topsoe’s technology licenses and the supply of engineering design, equipment, high-performance catalysts and technical services for ammonia, methanol and DME plants that are built, owned and operated by Air Products. It also allows for the integration of Topsoe’s technology into many Air Products’ technologies including gasification of various feedstocks, and synthesis gas processes.
Alistair Wallace, Head of Fertilizer Research, Argus Media, assesses price trends and the market outlook for nitrogen.
Many fertilizers plants are looking to reduce the overall maintenance costs of their critical heat exchangers. Barinder J. S. Ghai of Sandvik Materials Technology takes a look at the life cycle costs of tube materials for heat exchangers in ammonia plants.
Merchant ammonia capacity, only a relatively small 10% of overall ammonia demand, has been expanding in recent years and was already in surplus even before the current Covid crisis, but longer term a shortage of new projects may tighten the market again.
There is an urgent need to limit the rise in global temperatures to avoid severe environmental and societal impact. This can be expressed as a target to achieve net zero carbon emissions by 2050. The provision of decarbonised hydrogen at scale is an essential step in helping to achieve net zero. Johnson Matthey’s Low Carbon Hydrogen (LCH) technology permits the needs of scale and urgency to be met. J. Pach of Johnson Matthey presents a serious response to a serious threat.