Sulphur + Sulphuric Acid 2020
The coronavirus outbreak necessitated a ‘virtual’ CRU Sulphur + Sulphuric Acid conference last year, held in November 2020.
The coronavirus outbreak necessitated a ‘virtual’ CRU Sulphur + Sulphuric Acid conference last year, held in November 2020.
New approaches and novel processing schemes employing oxygen enrichment in sulphur recovery units have been developed and commercialised. In this feature Siirtec Nigi, Linde, Blasch, Fluor and RATE report on their latest developments.
A look back at some of the major events of 2020 for the sulphur and sulphuric acid industries, as well as a look forward as to how 2021 might look.
A few years ago DME production from methanol gave a major boost to world methanol demand, with DME being used as a blendstock for LPG. However, demand plateaued and DME has not had the takeoff that its proponents feel it should have. Could new renewable DME processes give it the boost it needs?
Enhanced efficiency fertilizers (EEFs) occupy a small but high-value segment of the overall fertilizer market, although their production and use is accelerating. This trend is unsurprising given that their higher costs are usually more than offset by better efficiency and lower application rates.
Spanish fertilizer producer Fertiberia is teaming up with energy firm Iberdrola to build Europe’s largest plant for generating green hydrogen for industrial use – in this case ammonia production. The 100MW solar plant and accompanying 20 MWh lithium-ion battery system and 20MW electrolytic hydrogen production system will be built at a cost of $174 million, and electrolyse water to produce 720 t/a of hydrogen. When fed into Fertiberia’s existing ammonia plant at Puertollano, 250km south of Madrid, the hydrogen will allow a 10% reduction in natural gas use by the plant, saving the company 39,000 t/a in annual CO 2 emissions. Start-up is planned for 2021. Fertiberia will also use electrolysis-generated oxygen as a raw material for nitric acid, which is used to produce ammonium nitrate at the site.
Falling costs for production of hydrogen by electrolysis are encouraging more serious consideration of using recovered carbon dioxide as a feedstock for chemicals and even fuels production.
The removal of hydrogen sulphide (H2 S) has become increasingly important as the oil and gas industry moves towards more efficient and sustainable production of lower emission clean fuels. BASF and ExxonMobil* have jointly developed a proprietary amine, OASE® sulfexx™ , to help refiners and gas processors achieve sulphur removal targets while reducing their carbon footprint via lower energy consumption. This new solvent technology is suitable for low and high pressure applications and shows superior performance characteristics over generic and promoted MDEA formulations, as well as sterically hindered amines such as FLEXSORB™ SE and SE Plus.
Merchant ammonia capacity, only a relatively small 10% of overall ammonia demand, has been expanding in recent years and was already in surplus even before the current Covid crisis, but longer term a shortage of new projects may tighten the market again.
We profile a selection of innovative speciality products and agronomic technologies that have recently been brought to market.