The production of syngas from hydrocarbon feedstock uses a number of catalytic steps to increase efficiency and maximise conversion while minimising energy consumption. In this article we report on the latest developments in water gas shift catalysis from Johnson Matthey, Clariant and Topsoe, and shift converter design from Casale.
Reducing carbon footprint in the synthesis of chemicals is a new challenge, a necessary requirement in the pursuit of sustainable products designed to minimise environmental impacts during their whole lifecycle. So-called “green” technologies for ammonia, methanol and hydrogen are being developed to meet these challenges. Casale, Linde, thyssenkrupp Industrial Solutions, Toyo Engineering Corporation, Haldor Topsoe and Stamicarbon report on some of their latest developments.
Rapidly escalating natural gas prices forced plant closures across Europe during September. Worst affected was the UK, where a fire at a cross-Channel electricity cable and low output from wind energy has, combined with low domestic storage capacity led to a surge in demand for gas for power stations and wholesale gas prices reached a record 350 pence per therm (equivalent to $46/ MMBtu) in October. On September 15th, CF Industries announced that it was halting operations at both its Billingham and Ince fertilizer plans due to high gas prices. Although ammonia prices have also risen, they have not kept pace with gas price rises, and there is a limit to what farmers could be expected to pay. CF CEO Anthony Will said: “$900 is the gas cost in a tonne of ammonia and the last trade in the ammonia market that was done was $700 a tonne”. As these plants supply most of the UK’s carbon dioxide for food and drink manufacture, the government said it would provide “limited financial support” to keep the Billingham plant operational, and that plant re-started on September 21st. Meanwhile, BASF closed its Antwerp and Ludwigshafen plants in Belgium and Germany due to what the company called “extremely challenging” economics. Fertiberia ceased production at its Palos de la Frontera site in Spain, and Puertellano remained down for scheduled maintenance. Yara shut 40% of its European ammonia production in September, and OCI partially closed its Geleen plant in the Netherlands. Achema in Lithuania decided against restarting its ammonia plant following maintenance in August, and OPZ in Ukraine shut one ammonia line at Odessa, with Ostchem and DniproAzot likely to follow. Borealis in Austria also reduced production.
New innovations and the latest equipment options from FEECO International, Casale, thyssenkrupp Fertilizer Technology and Eirich are helping to perfect the fertilizer finishing process.
Like the vital nitrogen fertilizer they handle, seasonal cheer will be in short supply for Europe’s ammonia producers and buyers this festive season, after many difficult months in which upward price trajectories showed no sign of slowing.
By utilising state-of-the-art technologies, nitric acid and ammonium nitrate producers are able to reduce the environmental impact of their production plants and make a key contribution to climate protection.
Maire Tecnimont SpA says that its subsidiaries MET Development, Stamicarbon and NextChem have collectively begun work on a renewable power-to-fertilizer plant in Kenya. MET Development has signed an agreement with Oserian Development Company for the development of the plant at the Oserian Two lakes Industrial Park, on the southern banks of Lake Naivasha, 100 km north of Nairobi.
Plans to decarbonise power production and shipping are leading to increasing interest in using ammonia as a fuel, but technical and economic barriers still remain to be overcome.
The internals of ammonia synthesis converters are generally made of austenitic stainless steel to withstand the harsh operating conditions (high temperature, high pressure and synthesis gas containing hydrogen and ammonia). Since nitriding is the most critical material degradation for the converter internals, Casale has set up a large nitriding analysis campaign. In the last decade, samples of materials operated under different pressures and temperatures and for different time spans have been tested and analysed. The data obtained has been used to increase nitriding knowledge and to establish a correlation to predict nitriding rate to allow the most suitable material and relevant thickness to be selected. L. Redaelli and G. Deodato of Casale report on how this correlation was established and provide valuable insight on this phenomenon and how to predict and control it.
We highlight the large-scale nitrogen projects that are currently under development across the globe – with a focus on ammonia and urea technology licensors and engineering contractors.