Chemetics describes a variety of ways to extend the life of sulphuric acid plants. Debottlenecking, emissions reduction and/or energy recovery projects require a systematic, phased approach to maximise the potential of economic and operational benefits to the owner.
Tightening regulations and growing global competition are increasing the pressure felt by sulphuric acid plant operators to reduce emissions and improve energy output. Conservation of energy is a continuous focus for operators, and environmental communities have grown more vocal in their desire for greater emissions oversight. In this article, DuPont Clean Technologies examines simple, tried, and true tactics, as well as new products and designs that can be incorporated into existing plants to address operating efficiency and emissions and to help to prolong the life of the plant.
INEOS Enterprises has announced the completion of the sale of its Sulphur Chemicals business to International Chemical Investors Group, for an undisclosed sum. INEOS Sulphur Chemicals business is Spain’s largest dedicated manufacturer of sulphuric acid and oleum, serving clients in both agriculture and chemical intermediates via its 400,000 t/a plant in Bilbao. The business will become part of WeylChem’s advanced intermediates and reagents portfolio, which includes an existing sulphuric acid and oleum plant located in Lamotte, northern France. WeylChem is wholly owned by the International Chemical Investors Group (ICIG).
Comprimo has recently launched two new solutions to make the most of existing data and to improve customer’s operations and customer knowhow: Comprimo Insight – an intelligent sulphur plant dashboard, and Comprimo Immerse – a dynamic sulphur plant simulator. In this article, Comprimo goes into the details of how Comprimo Insight and Comprimo Immerse are being implemented for its customers.
The internals of ammonia synthesis converters are generally made of austenitic stainless steel to withstand the harsh operating conditions (high temperature, high pressure and synthesis gas containing hydrogen and ammonia). Since nitriding is the most critical material degradation for the converter internals, Casale has set up a large nitriding analysis campaign. In the last decade, samples of materials operated under different pressures and temperatures and for different time spans have been tested and analysed. The data obtained has been used to increase nitriding knowledge and to establish a correlation to predict nitriding rate to allow the most suitable material and relevant thickness to be selected. L. Redaelli and G. Deodato of Casale report on how this correlation was established and provide valuable insight on this phenomenon and how to predict and control it.
M. Østberg and M. Rautenbach of Haldor Topsoe describe ReShift ™ technology, a new high temperature CO 2 reforming process, where preheated CO 2 is added directly downstream of a main reformer and then equilibrated in an adiabatic reactor. This new technology makes use of the high temperature of the reformer effluent to circumvent carbon formation, while at the same time maintaining an overall minimum steam to hydrocarbon carbon ratio, depending on process specific conditions. An increase in the amount of CO 2 added to the process will result in an increased fraction of CO in the produced synthesis gas. Synthesis gas with H 2 /CO ratios in the range 0.5-3 can be produced. These CO-rich gases are typically utilised in the production of functional chemicals and synthetic fuels.
With demand for conventional fuels projected to peak and fall over the next decade, some refiners are looking to petrochemical production as a way of diversifying their product slate.
The Abu Dhabi National Oil Company (ADNOC) has awarded a $510 million engineering, procurement and construction (EPC) contract to Italy’s Saipem to expand production capacity at the Shah sour gas plant, as the UAE looks to increase its output of gas by 2030. The Optimum Shah Gas Expansion (OSGE) & Gas Gathering project has been awarded by ADNOC Sour Gas, a joint venture between ADNOC and US energy major Occidental. The contract will increase gas processing capacity at the Shah plant by 13% per cent to 1.45 bcf/d from 1.28 bcf/d by 2023 and supports ADNOC’s objective of enabling gas self-sufficiency for the UAE. The Shah gas plant currently meets 12% of the UAE’s total supply of natural gas, as well as producing 5% of the world’s elemental sulphur. The expansion will cumulatively represent a 45% increase on the plant’s original capacity of 1.0 bcf/d when it came on-stream in 2015.
Developments in sulphuric acid technology and engineering know-how are highlighted by recent project case studies from DuPont Clean Technologies, Metso Outotec and thyssenkrupp Uhde.
Reducing the carbon footprint in the synthesis of chemicals is a new global challenge as the world works towards providing sustainable products designed to minimise their environmental impacts throughout their whole lifecycle. This article looks at the role of blue technologies as part of a roadmap towards the decarbonisation of fuels and chemicals.