Tag: Claus Tail Gas Treating

A complete listing of all articles and news items that appeared in Sulphur magazine during 2024.

As environmental SO2 emission regulations become more stringent, tail gas treating options become limited. To potentially achieve lower opex and improved plot plan, utilising a biological desulphurisation process as an alternative to a conventional amine-based TGT unit is becoming of increased interest in the oil and gas industry. At the same time, demands for increased SRU capacity and reliability favour the use of medium and high-level oxygen enrichment.

Cobalt-molybdenum (CoMo) catalysts are integral components of tail gas units (TGUs), playing a vital role in reducing harmful sulphur dioxide (SO2 ) emissions arising from Claus sulphur recovery units. Effective activation of these catalysts is essential for their optimal performance. The consequence of sulphiding at low temperatures and atmospheric pressure in low temperature TGUs is to compromise effectiveness of catalyst activation. In the final part of this two-part article, Michael Huffmaster , Consultant, presents case study results using a discrete reactor model incorporating heat, mass transfer, and activation reaction kinetics to assess the impacts of these variables on in-bed temperature profile and activation effectiveness. Tailoring gas rate, composition, and temperature progression can achieve in-bed exotherms which improve CoMo catalyst activation effectiveness for low temperature tail gas units.

Cobalt-molybdenum (CoMo) catalysts are integral components of tail gas units (TGUs), playing a vital role in reducing harmful sulphur dioxide (SO2 ) emissions arising from Claus sulphur recovery units. Effective activation of these catalysts is essential for their optimal performance. The consequence of sulphiding at low temperatures and atmospheric pressure in low temperature TGUs is to compromise effectiveness of catalyst activation. In the first part of this two-part article, Michael Huffmaster , Consultant, explores CoMo catalyst activation at low pressure, focusing on sulphiding reaction pathways and the impact of temperature and the composition of the sulphiding media on reaction kinetics, specifically the concentration of H2 , H2 S, and H2 O.

With the aid of a rigorous kinetic model for TGU hydrogenation reactors, incorporating catalyst deactivation mechanisms, designers and operators can forecast the life expectancy of reactor catalyst beds.

With the challenges facing the global refining industry, refiners should review their current practices to see how they can stay competitive and continue to thrive in today’s market. This means improving operational efficiencies and producing products at a lower cost, whilst ensuring performance and safety. Brian Visioli of Evonik explores the development of catalyst reuse and how recycled hydroprocessing catalysts can be successfully applied in tail gas treating units to deliver cost and performance gains.

SO2 breakthroughs remain an ever present threat to the successful operation of reductive, quenchamine-based tail gas clean-up units (TGUs). Effects can range from mild and annoying to quite severe, including failure to comply with environmental permit regulations and refinery shutdown. G . Simon A. Weiland, Nathan A. Hatcher, Prashanth Chandran, Daryl Jensen, Ralph H. Weiland, Jeff Weinfeld of Optimized Gas Treating, Inc. and Michael Huffmaster , Consultant.

Decreasing the carbon intensity of sulphur recovery is one of the many actions that operators can take to help meet their climate ambitions. It is also becoming increasingly rewarding financially because of the rising cost of carbon emissions. In this article, G. Kidambi of Shell Projects & Technology demonstrates the potential to cut the carbon intensity of tail gas treating units by more than 50% through swapping to the latest SCOT ULTRA amine solvent and catalyst technologies.

The removal of hydrogen sulphide (H2 S) has become increasingly important as the oil and gas industry moves towards more efficient and sustainable production of lower emission clean fuels. BASF and ExxonMobil* have jointly developed a proprietary amine, OASE® sulfexx™ , to help refiners and gas processors achieve sulphur removal targets while reducing their carbon footprint via lower energy consumption. This new solvent technology is suitable for low and high pressure applications and shows superior performance characteristics over generic and promoted MDEA formulations, as well as sterically hindered amines such as FLEXSORB™ SE and SE Plus.

BASF has developed a new generation of promoter system compatible with MDEA solutions named OASE® yellow. The new promoter system increases the selectivity and capacity of the amine solvent, resulting in improved performance of tail gas treating units and allowing the processing of more sour crudes. A. Kern and G. Vorberg of BASF discuss two case studies demonstrating the benefits of OASE yellow.