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Tag: Hydrogen

Nitriding in ammonia converters: behaviour, experience, and solution

The internals of ammonia synthesis converters are generally made of austenitic stainless steel to withstand the harsh operating conditions (high temperature, high pressure and synthesis gas containing hydrogen and ammonia). Since nitriding is the most critical material degradation for the converter internals, Casale has set up a large nitriding analysis campaign. In the last decade, samples of materials operated under different pressures and temperatures and for different time spans have been tested and analysed. The data obtained has been used to increase nitriding knowledge and to establish a correlation to predict nitriding rate to allow the most suitable material and relevant thickness to be selected. L. Redaelli and G. Deodato of Casale report on how this correlation was established and provide valuable insight on this phenomenon and how to predict and control it.

Converting CO2 to valuable synthesis gas

M. Østberg and M. Rautenbach of Haldor Topsoe describe ReShift ™ technology, a new high temperature CO 2 reforming process, where preheated CO 2 is added directly downstream of a main reformer and then equilibrated in an adiabatic reactor. This new technology makes use of the high temperature of the reformer effluent to circumvent carbon formation, while at the same time maintaining an overall minimum steam to hydrocarbon carbon ratio, depending on process specific conditions. An increase in the amount of CO 2 added to the process will result in an increased fraction of CO in the produced synthesis gas. Synthesis gas with H 2 /CO ratios in the range 0.5-3 can be produced. These CO-rich gases are typically utilised in the production of functional chemicals and synthetic fuels.

Nitrogen Industry News Roundup

The Chemical & Process Technologies business unit of thyssenkrupp Industrial Solutions is celebrating a milestone in 2021. It is one hundred years since engineer and entrepreneur Friedrich Uhde founded his own plant engineering company in a barn at his parents-in-law’s farm in Dortmund-Bövinghausen on April 6th, 1921. Now, in this centenary year, the origins of the firm are to become visible in its name again: thyssenkrupp is changing the business unit’s name to thyssenkrupp Uhde.