Tag: Hydrogen

Sour gas processing presents a number of unique challenges, especially at high levels of hydrogen sulphide and carbon dioxide content.

Euro Support’s new generation, titania-based low temperature tail gas catalyst shows a marked robustness to the start-up procedure compared to its common alumina-based counterparts. Dr B. Hereijgers of Euro Support discusses the promising lab results.

Storm Uri which blanketed the southern states of the US with snow, and led to widespread power outages in Texas, has had a major impact upon US Gulf Coast and Southern-Midwest refined products supply. Most Gulf Coast refineries were shut down or forced to operate at reduced rates. IHS Markit estimated that more than 5.2 million bbl/d of Gulf Coast capacity and 730,000 bbl/d in PADD 2 was impacted by the winter weather at its height, and close to 20% of lower 48 US natural gas production was shut-in in the first half of February. A drop in crude oil production of between 2.2 and 4 million bbl/d was estimated.

It can’t have escaped anyone’s notice that the question of the carbon intensity of ammonia and downstream nitrogen compound production has been one of the main industry talking points for the past year. Everyone seems to be talking about ammonia of different colours – green ammonia, blue ammonia, and all shades of turquoise in between. If you are confused, it may not be surprising, as these words have come to cover a wide variety of different methods and technologies for producing ammonia, and their green credentials consequently come in a whole range of different shades.

NOx emissions from chemical processes such as steam methane reforming contribute to air pollution. The chemical industry is required to take steps to lower such emissions. Technology, developed for related industries, can be designed and optimised to reduce NOx emissions from steam methane reformers. Emission control experts can use a combination of modelling and experience to guide plant operators in recommending and designing optimum, sometimes tailor-made solutions. In this article different options are discussed including low NOx burners, selective catalytic reduction, selective non-catalytic reduction and high emissivity ceramic coatings.

Johnson Matthey (JM) has secured a multiple licence for China’s Ningxia Baofeng Energy Group’s latest project to develop five of the largest single train methanol plants in the world. Located at Baofeng’s Ordos City complex in Inner Mongolia, the five plants each have a planned capacity 7,200 t/d. Under the agreement Johnson Matthey will be the licensor of all five plants and supplier of associated engineering, technical review, commissioning assistance, and catalyst. The plants will take synthesis gas as a feed and use JM radial steam raising converters in a patented series loop. Within the design, there is potential for 1-2% more feedstock efficiency over the life of the catalyst. Thanks to JM’s methanol loop synthesis technology, the plants will provide enhanced energy savings along with low OPEX, CAPEX and emissions. When complete, the plants will represent JM’s 13th operating license in China for a mega-scale plant (>5,500 t/d) and the fourth JM methanol design licensed by Ningxia Baofeng Energy.

Building on its long experience and leading position within global ammonia production, logistics and trade, Yara says that it aims to capture opportunities in green shipping, agriculture and industrial applications; a market expected to grow by 60% over the next two decades. A major first step includes plans to fully electrify its ammonia plant at Porsgrunn, Norway, with the potential to cut 800,000 t/a of CO 2 , equivalent to the emissions from 300,000 passenger cars.

In a carbon-constrained world, carbon capture and utilisation or storage (CCUS) installed on a methanol plant is a necessary and feasible solution. The new, patented AdWinMethanol CC® technology, jointly developed by thyssenkrupp Industrial Solutions AG and GasConTec GmbH, integrates carbon capture into large-scale, natural gas-fuelled methanol production to yield a drastically reduced carbon footprint. U. Koss and W. Balthasar of GasConTec and J. Wagner of thyssenkrupp Industrial Solutions discuss how it removes CO 2 emissions in an efficient, cost effective, and environmentally friendly manner, taking advantage of the design features of AdWinMethanol ® .

Process and simulation models can be valuable tools when troubleshooting to solve operational issues in sulphur recovery units. Two examples are provided. In the first case study it is shown how a tuned model was useful in troubleshooting an SRU that was experiencing lower than expected recovery efficiency and apparent channelling in the first catalytic converter. In the second case study an SRU simulation tool is used to investigate sulphidic corrosion in a waste heat boiler.

Fires are known to occur in sulphur storage pits and tanks somewhat frequently due to the presence of both flammable material and air, so methods for preventing and extinguishing these fires are critical. D. J. Sachde, K. E. McIntush, C. M. Beitler, and D. L. Mamrosh of Trimeric Corporation review fire suppression methods used in the industry including snuffing/sealing steam, rapid sealing, water mist, and inert gas blanketing. Protective tank design features to reduce the likelihood of a sulphur fire are also reviewed. Benefits and limitations, design considerations, and recommended guidance for suppression and preventative measures are discussed.