By using a Rectisol™ demonstration unit at one of Air Liquide’s industrial production sites, Air Liquide Engineering & Construction has gained unique know-how in Rectisol™ column design with structured packings. S. Schmidt, R. Szabo, M. Linicus and S. Corbet report on how the application of commercially available structured packings in the absorber columns of a Rectisol™ unit results in significant capex and opex savings.
Judging by the pages of the project announcements in our news section, you’d be forgiven for thinking that the ammonia and methanol industries were all running off hydrogen generated from electrolysis, and that we had already entered an era of ‘clean’ chemical generation which did not require fossil fuels as a feedstock. Of course, while companies can naturally be forgiven for wanting to put the best public face on their green credentials, it does obscure the fact that for the moment 99% of syngas generation comes from natural gas, coal, and some coke or naphtha.
Reducing the carbon footprint in the synthesis of chemicals is a new global challenge as the world works towards providing sustainable products designed to minimise their environmental impacts throughout their whole lifecycle. This article looks at the role of blue technologies as part of a roadmap towards the decarbonisation of fuels and chemicals.
N. Clark, B. Avancini and V. Sturm of Clark Solutions discuss a novel technology, SAFEHX® , providing a new approach to the cooling of strong sulphuric acid. Prototype results are shown and indicate a safe and stable cost-effective technology. SAFEHX® can be extended to every heat exchanger system where corrosion, mixture risks, fouling, process liquid loss (or contamination) and temperature control are key concerns.
With the sulphur content of crude oil and natural gas on the increase and with the ever-tightening sulphur content in fuels, refiners and gas processors will require additional sulphur recovery capacity. At the same time, environmental regulatory agencies of many countries continue to promulgate more stringent standards for sulphur emissions from oil, gas and chemical processing facilities. Rameshni & Associates Technology and Engineering discusses options for compliance with new regulations on emissions regarding IMO 2020 compliance and report on the results and evaluation of three case studies. Worley Comprimo reports on the revamp of a sulphur complex built in the late 1980s at a refinery in East Asia with the aim to increase the capacity, improve the availability and reliability and make the unit environmental compliant.
With declining ore grade feed to a metallurgical smelting process comes an increase in impurity load in the gas cleaning/acid process chain. K. Hasselwander, L. Skilling and C. Bartlett of Metso Outotec discuss a range of process solutions and how to maintain high productivity while keeping costs in check.
Ammonia synthesis catalysts have long lives and catalyst replacement is an infrequent activity. Many people will go through their careers in the ammonia industry without ever having to replace a synthesis catalyst and the infrequent nature of catalyst replacement means that many plants may not have direct experience of this activity. Ammonia synthesis catalyst can present a range of hazards throughout the replacement process, from transport through loading, reduction, start-up, shutdown and discharge, but the good practice illustrated in this article, and collaboration between catalyst suppliers and end users can ensure safe and successful catalyst changeouts.
The ammonia industry seems to have quite a buzz about it at the moment. As can be glimpsed in our Nitrogen Industry News section this issue, the number of proposed green ammonia production sites continues to grow, as does interest in ammonia as a hydrogen or energy carrier, while the shipping sector continues to seriously consider ammonia as a green fuel candidate for the longer term. The latter prospect could see current ammonia demand double by 2050, although as our article on sustainable nitrogen production on page 22 notes, whether enough renewable power will exist by then to generate that must be seriously doubted.
Georgy Eliseev , Principal Analyst at Fertecon for IHS Markit, looks at the medium to long term outlook for both ‘green’ and ‘blue’ ammonia production.
The Nigerian National Petroleum Corporation (NNPC) says that it plans to build a $3 billion methanol plant on Brass Island in the Niger Delta to produce up to 10,000 t/d of methanol using from gas supplied by Shell. A final investment decision was made by NNPC, DSV Engineering and the Nigerian Content Development and Monitoring Board, a state agency set up to ensure Nigerian involvement in oil and gas projects. Around 70% of funding for the project will come from international lenders, including the China Export-Import Bank, the African Development Bank and international commercial banks, with the rest funded from an equity issue. BP has signed a 10 year offtake deal for the plant’s output with the Brass Fertilizer & Petrochemical Company, the entity set up to operate the plant. Construction of the plant is expected to be completed by 2025.