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Tag: Hydrogen

Caustic scrubbing of molten sulphur vent streams

With increasing frequency, companies that have molten sulphur on site must put environmental controls on the vent streams from molten sulphur pits, storage tanks and loading operations. This article* describes the typical characteristics of molten sulphur vent gas streams as well as some of the important chemistry related to these systems in caustic scrubbers. Solids deposition issues observed in the field with caustic scrubbers operating on actual molten sulphur vent gas streams are presented. Design and operational strategies to mitigate plugging in molten sulphur vent gas scrubbers are also summarised in this article by D. J. Sachde, K. E. McIntush, D. L. Mamrosh , and C. M. Beitler of Trimeric Corporation.

Syngas News

Air Products and Haldor Topsoe have signed a global alliance agreement. Under the terms of the agreement the two companies will use their combined market network for developing potential projects and the combination of their expertise on large-scale ammonia, methanol and/or dimethyl ether (DME) plants to be developed and built globally. It gives Air Products access to Topsoe’s technology licenses and the supply of engineering design, equipment, high-performance catalysts and technical services for ammonia, methanol and DME plants that are built, owned and operated by Air Products. It also allows for the integration of Topsoe’s technology into many Air Products’ technologies including gasification of various feedstocks, and synthesis gas processes.

Reducing the CO2 intensity of hydrogen production

There is an urgent need to limit the rise in global temperatures to avoid severe environmental and societal impact. This can be expressed as a target to achieve net zero carbon emissions by 2050. The provision of decarbonised hydrogen at scale is an essential step in helping to achieve net zero. Johnson Matthey’s Low Carbon Hydrogen (LCH) technology permits the needs of scale and urgency to be met. J. Pach of Johnson Matthey presents a serious response to a serious threat.

Hydrogen for fuel cell vehicles and stationary power

As the world focuses on clean fuels for the 21st century, there is an emerging opportunity to use ammonia as a source of hydrogen. Hydrogen fuel cells are expected to play a significant role as part of a clean energy portfolio. T2M Global and its development partner, SAFCell, are collaborating to develop a modular system to produce hydrogen from ammonia using a novel solid state separation system that does not require pressure or solvents. P. Patel of T2M Global, C. Chisholm of SAFCell and V. Pattabathula of Incitec Pivot explain the challenges, the opportunities and the current status of this new technology.

Sulphuric Acid News

Shell Global Solutions International BV (Shell) has awarded Worley two contracts for PT Pertamina EP Cepu’s (PEPC) new sulphuric acid plant in Indonesia. This plant is part of the Jambaran-Tiung Biru utilised gas field project for PEPC, which is a subsidiary of PT Pertamina-Indonesia’s state-owned energy company. Under the contracts, Worley will supply be supplying Chemetics’ cooled oxidation reactor (CORE) technology. This is the first time that CORE will be paired with Shell’s Cansolv SO2 capture technology. Worley gained the Chemetics technology as part of its Jacobs Energy, Chemicals and Resources acquisition last year. Cansolv controls the emissions and captures additional by-product value from the sulphur dioxide emitted from various refinery flue gas streams (such as cracking units, process heaters and boilers), sulphur plants and spent acid regeneration units. Sulphur dioxide can be recycled to the sulphur recovery unit to be produced as marketable sulphur or converted to sulphuric acid.

Degradation of chemical additives under downhole conditions

When producing from shale reservoirs, technologies such as horizontal drilling and hydraulic fracturing have been used successfully to access hydrocarbons that otherwise could not be. A less publicised issue in producing from certain hot shale gas reservoirs (T > 100°C) is the presence of H2 S and organo-sulphur compounds in the production fluids. In trying to understand the non-biogenic sources of H2 S, Alberta Sulphur Research Ltd has been involved in studying the decomposition of chemicals used in hydraulic fracturing when exposed to high temperature and high pressure.R.A. Marriott, J.J. Marrugo-Hernandez and R. Prinsloo of ASRL discuss the findings of the study.