Tag: RATE

Johnson Matthey’s latest methanol synthesis catalyst, KATALCO™ 51-102, was introduced in 2018 to offer improved catalyst stability and therefore higher end-of-life activity and extended lifetimes than conventional methanol synthesis catalysts. Since launch, KATALCO 51-102 has been successfully installed in two methanol plants and a third is planned for later in the year. In this article Johnson Matthey provides an update on the proven performance of KATALCO 51-102 during lab and pilot scale testing as well as in customer plants. The application of catalysts made using the KATALCO 51-102 technology for methanol synthesis via new ‘green’ routes, such as using captured and purified CO2 in conjunction with ‘green’ hydrogen, is also discussed.

Johnson Matthey and MyRechemical have formed an alliance to commercially develop waste to methanol technology. In this article, two different approaches to waste disposal and chemical production are analysed: a post combustion scenario with waste incineration and hydrogenation of the CO2 recovered from flue gas to produce methanol, and a precombustion approach with waste gasification followed by conversion of synthesis gas into methanol.

MegaZonE™ is a newly introduced layered loading technology for boiling water-cooled reactors used for methanol synthesis. This new concept is one of the latest results of the long-standing collaboration between Air Liquide Engineering & Construction and Clariant Catalysts to improve the methanol process flowsheet and optimise catalyst performance in the complete reactor system.

India’s power and renewable energy minister RK Singh has placed draft plans before the cabinet for the country’s refining and fertilizer sectors to switch to renewable ‘green’ hydrogen feeds. Other energy intensive sectors such as steel and transport are likely to follow. The policy suggests that refiners must have 10% of their hydrogen consumption generated from renewable electricity by the end of financial year 2023-24, rising to 25% by 2030. The comparable figures for ammonia/urea production are 5% and 20%, respectively. India is pursuing some of the world’s most ambitious renewable energy targets of 175 GW of renewable energy capacity by the end of 2022 and 450 GW by 2030.

Tightening regulations and growing global competition are increasing the pressure felt by sulphuric acid plant operators to reduce emissions and improve energy output. Conservation of energy is a continuous focus for operators, and environmental communities have grown more vocal in their desire for greater emissions oversight. In this article, DuPont Clean Technologies examines simple, tried, and true tactics, as well as new products and designs that can be incorporated into existing plants to address operating efficiency and emissions and to help to prolong the life of the plant.

ASRL has conducted studies on ammonia destruction in the sulphur recovery unit (SRU) for over a decade1-5 . Other studies at ASRL have investigated mechanisms for ammonium salt formation and deposition downstream in the Claus plant, as well as the potential sources of ammonia (NH3 )in a gas plant7 . A less understood subject is addressing how much residual NH3 is tolerable or at what temperature will residual NH3 cause ammonium salt deposition. In this study, existing knowledge on thermal stability of ammonium salts and new measurements have been used to identify the gaseous components required for deposition, through reversible vapour pressure expressions.

Dealing with sulphur dust is an operational challenge for sulphur forming plants and sulphur storage and handling facilities.

Corrosion is one of the most critical aspects regarding sulphuric acid plant lifespan. One important cause of corrosion in sulphuric acid plants is acid condensation from the process gas due to inadequate drying. E. Almeida, B. Ferraro, N. Clark, V. Machida and V. Sturm of Clark Solutions discuss this problem and how it can be avoided with proper tower and internals design.

The delivery of nitrogen in nitrate form can deliver superior yields and quality in arable, fruit and vegetable crops. Because of this, production and consumption of the principal nitrate fertilizers – ammonium nitrate (AN), calcium ammonium nitrate (CAN), urea ammonium nitrate (UAN), potassium nitrate (NOP) and calcium nitrate (CN) – continue to grow.

A holistic understanding of the phosphate milling process is necessary, says Ian Hancock of Bradley Pulverizer. This ensures maximum plant uptime, the highest process efficiencies, and ultimately guarantees profitability.