Inshan S. Mohammed of Sulfur Recovery Engineering shares lessons learned from a recent SRU shutdown assistance programme involving an error with the tags used within the BMS system installed on a direct-fired reheater.
T he end of August saw a paper published in the Journal of the Royal Geographical Society by Dr Mark Maslin of University College London. Widely reported, it looked at the prospects for sulphur production in an era of declining fossil fuel use, concluding that there could be “a shortfall in the annual supply of sulphuric acid of between 100 and 320 million tonnes by 2040, depending on how quickly decarbonisation occurs”. It added that “unless action is taken to reduce the need for sulphuric acid, a massive increase in environmentally damaging mining will be required to fulfil this resource demand.”
Marco van Son and Frank Bela of Comprimo share lessons learned from SRU war stories, including: inadvertent NH3 destruction in an oxidising atmosphere, rich amine emulsion, SWS fixed valve trays, H2 spiking of SRU feed, rich amine flash drum early warning, V-ball fuel gas safety shutoff valves, TGTU methyl mercaptan, and commissioning and Murphy’s Law.
Temperature dependent rate constants for the hydrolysis of CS2 and COS across Claus Al2 O3 and TiO2 catalysts are valuable tools for the design and optimisation of new, as well as existing, sulphur recovery units. In this context, Alberta Sulphur Research Ltd (ASRL) has measured CS2 and COS hydrolysis rates over a range of temperatures for both Al2 O3 and TiO2 catalysts under start-of-run and, more recently, end-of-run first converter conditions. In this article Christopher Lavery, Dao Li, Ruohong Sui, and Robert A. Marriott of ASRL report on their methodology and the utility of the kinetics calculated from their data and draw comparisons between the start-of-run and end-of-run results.
The past couple of years have been quite the wild ride, with major global events dominating markets outside of the usual concerns of broad market supply and demand. It seems like a long time ago now, but this time last year, the price of a barrel of Brent crude was about $75. Go back two years, in the wake of the onset of covid restrictions, and that barrel would have cost you $40 (and just $25 a couple of months before that). In the wake of Russia’s attack on Ukraine, you could easily have paid $130, and it has been hovering around $110/bbl for the past few months. The last time oil spent any time at that level was in 2014, just before the Chinese economy ran out of steam and prices slumped by 70%.
More than 400 representatives from across the global sulphur community convened in Abu Dhabi from 24-26 May 2022 for an exciting new event, the Middle East Sulphur Conference, devoted to exploring best practice operations across the entire sour gas and sulphur value chain.
M. Rameshni and S. Santo of Rameshni & Associated Technology & Engineering (RATE USA) report on advanced catalysts for increasing the sulphur recovery efficiency of new and existing sulphur recovery units to meet stricter environmental regulations.
Most inspection personnel are familiar with the symptoms of process-related issues; however, they often lack an understanding of the root causes of water-related issues. In this article L. Huchler of MarTech Systems and E. Nasato of Nasato Consulting provide insight about early warning signs of common water-related failures in steam generators and sulphur condensers, proactive monitoring practices, practical operating strategies, options for corrective actions, reminders about robust water-side design and reminders about the challenges of prematurely destroying evidence by prioritising cleaning over diagnostic efforts during turnaround activities.
The Sulphur Community is set to reconvene in Abu Dhabi. CRU and UniverSUL Consulting, with the support of ADNOC, are hosting a new live event, Middle East Sulphur Conference (MEScon), which will take place at the Rosewood Abu Dhabi from 24-26 May 2022.
The trend for multicomponent analysis of emissions from sulphur recovery units is becoming more widespread. David Inward of Sick reports on a recent field trial to test the suitability of a hot extractive infra-red analyser for this application. In addition to reliably measuring and reporting emissions to air, the analyser is also capable of contributing to reducing overall tail gas emissions by supporting enhanced optimisation of the thermal oxidiser.