This case study reports on the successful collaboration of two experienced partner companies to replace the problematic upper part of a co-current flow quench tower in a spent acid plant and shows the benefits of using resistant, pre-lined workshop fabricated equipment.
Sulphur prices are expected to increase during H1 2024, reversing the trend of recent declines, though good availability will limit the upside to price gains in the short term. However, should fertilizer production prove weaker than expected, prices may remain below expected levels.
The cadmium and heavy metal content of sedimentary phosphates are of great concern. This has seen industry raw material consumption shift towards igneous phosphates or the blending of phosphate rocks from different sources. While rock blending can successfully reduce the heavy metal content of superphosphates, it needs to be accompanied by careful process adjustments, as Ian Hancock , Bradley Pulverizer’s vice president sales & operations, explains.
Volatility in sulphur prices has been reduced in the past year following the large price spike and subsequent drop in the summer of 2022. This price volatility has been due to various disrupted seasonal trends from the global pandemic, uneven recovery, geopolitical shifts and demand destruction for fertilizers.
First Quantum Minerals Ltd. has contracted with MECS, Inc. (MECS), a subsidiary of Elessent Clean Technologies, for the Kansanshi smelter expansion at the Kansanshi mine at Solwezi. MECS’ scope of work will include a redesign of the existing sulphur-burning sulphuric acid plant into a copper smelter off-gas recovery sulphuric acid plant. This transition to a copper smelter off-gas recovery acid plant will enable First Quantum to reduce emissions from the existing copper smelter, increase production at the mine, and supply more copper to the global market, which will enable the adoption of greener technologies. MECS’ design for First Quantum incorporates proprietary technologies such as MECS® catalyst for low emissions and high conversion, Brink® mist eliminators, ZeCor® alloy towers and pump tank and UniFlo® acid distributor technology for operational reliability and efficiency.
Market Intelligence Price Indications Table 1: Recent sulphur prices, major markets
The merchant market for sulphuric acid is only a small slice of overall global acid demand, dominated by smelter acid producers. Increasing replacement of acid imports by dedicated sulphur burning acid plants by end use consumers is reducing the scope for merchant sales and could lead to overcapacity in the near term.
A sulphuric acid plant in Northwest China is looking to capture its low-grade heat for re-use. With the support of Alfa Laval’s semi-welded plate heat exchangers and energy recovery expertise, in winter, all of the recovered low-grade heat could be put back into their system with 30% being used in production and the remaining 70% going to heating. During the summer, 14% of the energy that is no longer needed for indoor heating could be used to preheat boiler feedwater. This would enable them to significantly reduce the amount of fossil fuels used in production, without redesigning their entire factory footprint.
A report on CRU’s annual Sulphur + Sulphuric Acid conference, held in New Orleans, USA, 6-8 November 2023.
A softer trend in DAP prices, linked to lower operating rates in China and declining demand, is contributing to falling sulphur prices.