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Tag: Sulphur

A smarter way to treat lean sulphurous off-gases

The implementation of WSA technology to recover sulphur as sulphuric acid from lean sulphurous off-gases offers significant environmental benefits. These include waste reduction, resource efficiency and reduced overall CO2 e footprint, while also producing profitable sulphuric acid. By embracing such practices, industries can ensure improved or better consumption and production patterns and foster a more sustainable and responsible future. J. Feddersen and S. S. Johansson of Topsoe illustrate these benefits using three distinct industrial applications where WSA technology provides a smarter way to treat sulphurous off-gases. It is not only waste stream management in the three cases, but also reduced transportation of chemicals, reduced opex and reduced CO2 e footprint.

Ultra capacity with ultra low emissions

As environmental SO2 emission regulations become more stringent, tail gas treating options become limited. To potentially achieve lower opex and improved plot plan, utilising a biological desulphurisation process as an alternative to a conventional amine-based TGT unit is becoming of increased interest in the oil and gas industry. At the same time, demands for increased SRU capacity and reliability favour the use of medium and high-level oxygen enrichment.

Cobalt-molybdenum catalyst activation in low temperature TGUs

Cobalt-molybdenum (CoMo) catalysts are integral components of tail gas units (TGUs), playing a vital role in reducing harmful sulphur dioxide (SO2 ) emissions arising from Claus sulphur recovery units. Effective activation of these catalysts is essential for their optimal performance. The consequence of sulphiding at low temperatures and atmospheric pressure in low temperature TGUs is to compromise effectiveness of catalyst activation. In the final part of this two-part article, Michael Huffmaster , Consultant, presents case study results using a discrete reactor model incorporating heat, mass transfer, and activation reaction kinetics to assess the impacts of these variables on in-bed temperature profile and activation effectiveness. Tailoring gas rate, composition, and temperature progression can achieve in-bed exotherms which improve CoMo catalyst activation effectiveness for low temperature tail gas units.