Paralloy has developed Omega technology, an advanced reformer tube design that enhances heat transfer, gas turbulence, and process efficiency. Dr Dominique Flahaut of Paralloy explores the real-world implications of Omega reformer tubes.
Syngas generation units (SGU) represent a large portion of the capital and operational expenditure of ammonia plants and are critical from a mechanical reliability standpoint. Related capex/opex optimisation and mitigation of possible operational problems are key targets for ammonia plant owners. Giovanni Manenti introduces NITROQUENCH® technology which focuses on these key targets for ammonia SGU.
While there is still a considerable push for use of biomass waste as a lower carbon feedstock for chemical production via gasification to syngas, biological processes such as fermentation are increasingly gaining traction as an alternative.
The reliability of primary reformers is a key issue for syngas plants. Quest Integrity describes the damage mechanisms and material limitations that impact the reliability of reformer outlet systems and the improvements that may be implemented.
Industrial plants using synthesis gas at elevated temperatures risk metal dusting attack on the equipment, which are typically made of steels or Ni-based alloys. Parameters which impact the metal dusting risk are discussed and factors affecting the material selection and processing are described. One important focus is surface preparation, showing that grinding (40 grit) improves the metal dusting resistance compared to glass bead blasting and brushing. The surface treatment outweighs the impact of welds or the manufacturing route.
Low carbon intensity hydrogen and ammonia production schemes from KBR, Air Liquide, Mitsubishi Heavy Industries, Casale and Johnson Matthey.
New methods for low-carbon ammonia production are emerging, while project activity is also rising rapidly.
Previously, recuperative reforming has been mostly applied for capacity increase revamps, but nowadays it is a key enabler for efficient low carbon hydrogen and syngas production. Jan-Jaap Riegman of Technip Energies, Francesco Baratto of Casale and Stefan Gebert of Clariant discuss the benefits of recuperative reforming for reducing the carbon footprint of existing assets.
Air Liquide presents the results of an internal study to identify preferred natural gas-based plant configurations at a methanol capacity of 250 t/d. Delivering small capacity plants requires a focus on the total cost of ownership (TCO) for the economics to be successful, in addition to the CO 2 footprint of the operation. As found by this study, SMR concepts are naturally power balanced for standalone greenfield operations and show no particular advantage for power import in a brownfield setting. POX and ATR cases are greatly improved and even advantaged in a brownfield setting compared to SMR when shifting from power balance to power import cases.
thyssenkrupp Industrial Solutions discusses a revamping concept to reduce CO2 emissions by replacing some of the hydrogen in the front end of the ammonia plant with green hydrogen, KBR and Casale report on revamp options to increase the capacity of vintage ammonia plants in the former Soviet Union, Johnson Matthey presents a novel integrated ammonia flowsheet for the production of ammonia, methanol, urea and UFC and Arvos | Schmidtsche Schack discusses the benefits of a new process gas boiler.