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Tag: Ureaknowhow

Plant Manager+

Storing urea under hot and humid ambient conditions can be a chall enge. Several quality parameters of the urea product itself like moisture, temperature and particle size distribution are critical. Fluctuations of these parameters over time are also important and can lead to caking issues and complaints by clients. Off-spec product means big losses in revenue and results in a troublesome stream that has to be handled separately. Learning from each other’s experiences is vital to minimise and avoid these problems. n

Plant Manager+

This UreaKnowHow.com round table discusses the process upset condition of a high urea concentration in the ammonium carbamate recycle. It is commonly known that the urea formation reaction from ammonia and carbon dioxide via ammonium carbamate is an equilibrium reaction and that the urea conversion in any urea plant is limited. That is why downstream of the urea synthesis section the urea is separated from the ammonium carbamate in a recirculation section. Ammonium carbamate is dissociated into ammonia and carbon dioxide gases by means of low pressure and the addition of heat. The ammonia and carbon dioxide gases are dissolved in water and recycled back to the urea synthesis section. The urea content should be minimal as urea in the ammonium carbamate recycle leads to lower efficiencies. What are the causes and remedies for a high urea concentration in the ammonium carbamate recycle? n

Plant Manager+

This case study refers to the carbamate condensers and separators in the urea recirculation and hydrolyser desorber section of a urea plant, operating under normal operation at 0.3 MPa and 75°C. After 48,000 hours of operation, during the turnaround of the urea plant, the diaphragm type instruments were sent to the original equipment manufacturer for inspection and refurbishment. In addition to damage of the diaphragm, crevice corrosion was found in the gasket area (see picture) posing a health and safety risk .