Fertilizer International 504 Sept-Oct 2021
30 September 2021
The benefits of boron
CROP NUTRITION
The benefits of boron
Boron is a key micronutrient required by fruit and vegetables and crops such as corn, cotton, rice, soybean and sugar cane. The agricultural importance of boron and the wide range of products on the market are described.
An attractive and growing market
Boron dominates the global agricultural market for micronutrients. The application of boron in agriculture reached 300,000 tonnes (B2 O3 ) in 2018, equivalent to around 15 percent of global consumption. That compares to total global sales volume of around 65,000 tonnes for chelated micronutrients1 .
The main boron-consuming regions are East Asia, Latin America and Europe (Figure 1). About 35 percent of Chinese soils are thought to be boron deficient. Brazil’s acid soils also tend to be deficient in boron as do the acid and sandy soils of Northern Europe.1
Boron is typically applied to crops at 0.25-3 kg/ha with higher rates generally required for broadcasting than for band applications or foliar sprays. Legumes and root crops usually require 2-4 kg/ha, while lower rates are advised for maximum yields in other crops2 .
Borax or other soluble borates are usually applied to soil before planting. These and other boron fertilizers should not be placed in direct contact with seeds or applied at levels that may be toxic to crops. Boron availability is negatively affected by drought conditions and the liming of acid soils2 .
The margin between deficiency and toxicity for boron is narrower than for other essential nutrients. That makes its application at the proper rate and with proper placement critical. Corn most effectively uses boron when it’s applied through broadcast applications to soil, although foliar applications can be superior in other annual crops2 .
Boron, while classed as a micronutrient, can deliver major improvements in crop yields. In trials commissioned by U.S. Borax and others, boron fertilizers have been shown to multiply corn yields and increase cotton yields by hundreds of kilos per hectare, for example. Yet boron deficiency remains one of the most widespread of all crop deficiencies globally, affecting many major crop types.
Essential for plant growth
Boron helps plants to synthesise structural carbohydrates and build strong, stable cell walls. Boron also enables sugars to form in leaves and then helps transport these to those parts of the plant where they are most needed – especially new growth and the root system.
In crops, boron plays a particularly vital role in the development of seeds and fruits – controlling flowering, pollination, reproduction, germination and fruit development. The formation of root nodules in legumes also depends on an adequate supply of boron.
Boron’s promotion of pollen tube growth is another key function. This is because successful pollination leads to good seed set and ultimately to abundant fruit, nut and grain yields. Boron’s many influences as a plant nutrient can be summarised as follows (Figure 2):
- Aids production of sugar and carbohydrates
- Enables the translocation of sugars within plants
- Regulates metabolism of carbohydrates
- Helps synthesise nucleic acids
- Essential for cell division and development
- Maintains integrity of root cell walls
- Speeds up the onset of plant maturity
- Essential for elongation of pollen tubes
- Improves seed set
- Essential for fruit set and development
- Required for nodulation and nitrogen fixation in legumes
- Enhances the uptake of other nutrients such as Ca, Mg and K.
Boron, by maintaining the function and structure of root cells, is linked to improved uptake of phosphorus and potassium from soil. It is also believed to play a role in root colonization by Mycorrhizal fungi, another influence on phosphorus uptake. There is also evidence to suggest that boron helps protect plants against aluminium toxicity in low pH soils.
Widespread deficiency
Boron deficiency is the second most widespread micronutrient deficiency in soils globally after zinc. Unsurprisingly, deficiency is particularly prevalent in those crops with higher-than-normal boron requirements. Notably boron-hungry crops include alfalfa, canola, coffee, corn, cotton, oil palm, olives, peanuts, rice, soybean, sugar beet, sugar cane and tree fruits.
Deficiency is mainly associated with soils low in organic matter and, due to the potential for boron leaching, coarse-textured and well-drained sandy soils. Soils with high nutrient adsorption and retention capacities
– such as high pH soils and those rich in clay minerals and iron or aluminium oxides
– can also cause crop deficiency.
Organic matter generally increases boron availability as it typically acts as a store for plant-available boron in soils. Boron deficiencies are exacerbated by low soil moisture and drought periods because of the general decrease in root activity. Balanced crop fertilization generally helps to optimise boron uptake by improving plant vigour and healthy root growth.
Signs of boron deficiency firstly appear at new growth points. Water absorption, root growth and translocation of sugars are all negatively affected. Deficiency is damaging as it commonly results in empty pollen grains, poor pollen vitality and a reduced number of flowers per plant. Low boron supply can also stunt root growth – in soybean and canola (rapeseed) crops, for example. Common deficiency symptoms in crops include:
- Poor seed set or fruit set
- Breakdown of growing tip
- Yellowing between veins on young leaves
- Stunted new growth and dieback of shoot tips in vegetables
- Short bushy cotton plants
- Missing kernels in corn
- Yellowish to reddish yellow discolouration of the terminal foliage in alfalfa
- Root crops such as beets and turnips develop a corky dark discolouration
- Poor Rhizobia development in the roots of legumes.
Selected products and producers
Notable suppliers of boron fertilizers include:
- U.S. Borax
- Eti Maden
- The Mosaic Company
- Koch Agronomic services
- Nachurs Alpine Solutions
- ATP Nutrition
- Omex.
It is no coincidence that many of these companies are North American, given that boron deficiency affects crop production and quality across the region, according to The Mosaic Company. To address this, Mosaic launched Aspire, a boron-enhanced potash fertilizer, in 2014 (Fertilizer International 486, p18). This first-of-its-kind premium potash fertilizer (0-0-58-0.5B) combines potassium chloride (58% K2 O) with boron (0.5%).
Aspire is formulated to provide season long boron availability by containing both quick-release sodium borate and slower release calcium borate. Boron is also uniformly distributed within potash granules using Mosaic’s proprietary Nutriform technology. Aspire is being targeted at crops such as alfalfa, corn, cotton, potato, sugar cane and soybean, and has demonstrated significant yield improvements for these crops in field trials (Fertilizer International 486, p18).
U.S. Borax is the world’s leading supplier of borates for agriculture. The company has conducted numerous agronomic studies and field trials for cultivated crops across the world, making it a technical leader in the industry. Part of London-based Rio Tinto Group, U.S. Borax operates California’s largest open pit mine at Boron in the Mojave Desert (see main photo). This is one of only two world-class borate deposits globally, and supplies nearly one third of the world’s demand for refined borates.
U.S. Borax constructed a boric acid plant at its Mojave site in 1980, helping secure the company’s position as the world’s leading boric acid producer. The company manufactures and markets three main products for use in agriculture: Fertibor® , Granubor® and Solubor. ®
Fertibor is a sodium borate (15.0% boron) used in the manufacture of ammoniated, granulated, and suspension fertilizers. It works best in fertilizer suspensions broadcast before planting but is also the main source of boron in compound NPK fertilizers. Granubor is a granulated form of sodium borate (14.3% boron) for use with bulk blended fertilizers. It is suitable for dry blends broadcasted prior to planting. Solubor is a soluble form of sodium borate (20.5% boron) designed for liquid fertilizers and foliar sprays. It can be dissolved in water and applied to soils or directly on crops, with or without pesticides.
U.S. Borax also launched two new fertilizer products, Anhybor® and Zincubor® , on the market earlier this year – see interview on page 36. These have been created for fertilizer blenders and other companies wishing to produce micronutrient-enriched products (Fertilizer International 503, p20).
Anhybor® is manufactured from borax using a dehydration and fusion process. The product can be used to coat the different fertilizer constituents of NPK blends, with the aid of a binder material, or applied directly to soils. The high boron content of Anhybor® is an advantage, according to U.S. Borax, as less product is required to reach the target boron level.
Zincubor® is a two-in-one product that helps avoid the negative effects of zinc deficiency. It combines zinc and boron in “a perfect 2:1 ratio to meet the exact zinc and boron demands of most crops”, says the company. Zincubor® can be used as a micronutrient coating for fertilizers, with the aid of a binder, or applied directly to soils. Valuably, the product can also be used to produce suspension fertilizers.
Omex MDS coatings
Boron is required for crop growth and reproduction. Deficiencies affecting more than 100 plant species have been reported in over 90 countries globally. Andrew Lawrence, export manager for fertilizer coatings at Omex Agrifluids, explains how boron deficiency and its impacts can be addressed.
During the early stages of crop development, boron deficiency will retard new growth and the development of roots, with symptoms usually showing in young leaves initially. As the crop develops, boron deficiency has clear negative effects on flowering response and pollination, leading to reduced seed, tuber, or fruit set. Maturation is often delayed, while reduced starch accumulation slows crop development and greatly increases the risk of structural problems in seeds and fruit. Boron deficiency is also associated with reduced tolerance to drought and heat stress, two factors which are likely to become more frequent due to climate change.
Hence, boron, alongside other nutrients, is acknowledged as being important to crop health. Calcium is another essential nutrient with a vital role to play in cell growth, development and tissue protection. By combining calcium with boron, to further enhance pollen tube elongation, it is possible to promote successful pollination and, crucially, avoiding unnecessary abortion of flowers. Recent product research by Omex Agrifluids has confirmed the important nutritional inter-relationship between boron and calcium. This realisation has enabled the company to move away from straight boron products and provide growers with more advanced product solutions that address broader nutritional requirements throughout the crop cycle.
It is well understood that addressing any lack of boron at the earliest possible stage of plant development pays dividends later. With this in mind, Omex’s calcium enriched MDS Boron product allows growers purchasing granular fertilizer to apply boron as a fertilizer coating saving time and effort during the planting season.
The application rate of MDS Boron (8% B w/w) can be quickly adjusted to correct any specific deficiency identified by soil testing, allowing custom applications to be easily applied while controlling input costs. As the crop advances, Omex Calcium Boron (15% Ca & 3% B w/v) and the solution fertilizer Omex Foliar Boron (11% B w/w with nitrogen) can be very effective at correcting any remaining deficiencies, especially during times of environmental stress.
MDS coatings are typically concentrated suspensions specifically formulated to evenly coat the surface of each fertilizer granule. These coatings, by providing accurate field distribution, make vital nutrients available at the earliest stage of crop development. Omex MDS coatings are very easy to apply commercially with existing blending equipment. Additionally, at small holder farm level, the manual coating of fertilizers is also possible with only minimal investment in equipment required.
Omex MDS coating products include the full range of micronutrients and are compatible with a wide range of granular fertilizers – including NPK blends, compounds, and straights. Furthermore, trace micronutrients, typically selenium, cobalt and molybdenum, can also be included with MDS for a safe and accurate application to fertilizer materials.
Eti Maden IGM is Turkey’s biggest national mining company. It was established in 1935 to take advantage of the country’s vast boron deposits – these holding almost three-quarters of world reserves. The company has since become the world’s leading boron minerals and boron chemicals producer, and the largest exporter of refined boron products and minerals globally.
Eti Maden – previously known as Etibank and Eti Holding – set up a joint venture (JV) with the Finnish mining and multi-metal company Outokumpu Group in 1982. Known as Ab Etiproducts Oy, being the first foreign entity of Eti Maden IGM, this Finland-based JV is responsible for the international marketing and sales of the boron products produced by Eti Maden. The company initially sold into the Scandinavian market, although its marketing and sales activities have expanded greatly over time. Ab Etiproducts Oy’s exclusive sales area now covers the Scandinavian and Baltic countries, Germany, Poland, Ukraine, Moldova, the whole of the African continent and Arab Gulf states.
To meet different crop requirements, Eti Maden offers several types of boron product in its agricultural portfolio. Boron can generally be provided to plants in two ways: typically being applied either in solid, granular form to soils; or in liquid form directly onto plant leaves. Agricultural products are generally either quickly dissolving sources of boron, such as Etidot-67 and boric acid, or slow-release granular products (2-4mm size) such as colemanite and ulexite. Eti Maden’s portfolio also includes such products as KBor, which contains one percent potassium chloride in combination with boric acid, and Etifert, a micronutrient fertilizer.
Application methods and product selection depend on several external factors, such as soil conditions, rainfall and the target crop. Ab Etiproducts Oy therefore always advises that an agronomist is consulted prior to application.
References
Maximising boron efficiency with Wolf Trax®
The coating product Wolf TraxBoron DDP® ® offered by Koch Agronomic Services (KAS) can supply boron efficiently to crops around the world, as Matias Ruffo, the company’s senior agronomist for Latin America, explains.
Globally, boron is the second most widely used micronutrient and can have a direct economic impact if a crop experiences a boron deficiency. Due to its behaviour in the soil and crop, it can be a difficult nutrient to manage. Much like other micronutrients, boron faces similar challenges when it comes to segregation and lack of uniform distribution when applying granular micronutrient fertilizers alone or in bulk blends.
For most crops, boron is immobile within the plant which means the best way to supply boron to meet crop demand throughout the season is through root uptake (soil application). In contrast to its immobility in the plant, boron is very mobile in the soil and can be lost due to leaching, especially in sandy soils, high rainfall areas or under irrigation. This makes it challenging to supply boron over the entire growing season (and typically requires annual applications). Since plants are not very effective in regulating boron uptake, there is a very small range of optimal boron availability because high soil boron concentrations can result in phytotoxicity. This makes it critical to have a uniform boron distribution across the field.
To help address these management challenges, Wolf TraxBoron DDP® ® (dry dispersible powder) is one solution capable of efficiently supplying boron to crops around the world. Wolf Trax Boron DDP features three exclusive proprietary technologies, Evencoat® , Plantactiv® and Dual Action, that help to efficiently deliver the boron nutrition that today’s crops require to meet their genetic yield potential.
Boron and other micronutrients, when applied in bulk blends with macronutrients (NPKs), can suffer from segregation, resulting in uneven application rates of the micronutrient in the field. The Evencoat technology featured in Wolf Trax products ensures that boron is thoroughly and homogenously coated onto each granule of the fertilizer blend, thus eliminating the risk of segregation and its negative effects. With Wolf Trax Boron DDP, boron gets applied over the entire field at the precise and accurate rate.
Even when segregation is minimsed, bulk blends which incorporate granular boron products result in uneven distribution, with only a few granules of boron per square foot. This creates two issues. Firstly, the creation of high boron concentration ‘hot spots’ can cause phytotoxicity (which is typically not an issue for other micronutrients) where the boron granule falls. Secondly, very few ‘feeding points’ are available where roots can take up boron. This has a knock-on effect on crop nutrition – and explains why the typical boron application rate is much higher than the crop’s actual requirements.
In contrast, the uniform, even distribution of boron achieved by coating every fertilizer granule with Wolf Trax Boron DDP results in more points of interception for the plant’s roots to take up boron. This gain in efficiency allows for lower concentration rates compared to bulk blends. In addition, with Wolf Trax Boron DDP, the risk of boron toxicity is minimized as it doesn’t generate the ‘hot spots’ that can occur with bulk blend applications.
As mentioned earlier, unlike other micronutrients such as, zinc or copper, boron is highly mobile in the soil profile and can leach past the root zone, particularly in sandy soils which are also typically boron deficient. Therefore, applying a highly soluble boron fertilizer can be cause for concern since it can be lost and, in some situations, lead to toxicity. Conversely, using a less soluble boron source has the risk of not supplying the boron that rapidly growing crops demand to reach high yields. To address these issues, Wolf Trax Boron DDP is formulated to safely deliver boron to crops throughout the growing season. The technologies found in Wolf Trax products provide three forms of boron with a range of solubilities to help ensure nutrients are available when crops need it most.
To help meet crop nutrient demands, Wolf Trax Boron DDP technology also provides unparalleled flexibility when it comes to customising the formulation to suit individual fields and crops. Conversely, compound or complex fertilizers that only supply boron at a fixed micronutrient-to-macronutrient ratio make it difficult to apply boron at the right rate.
To summarise, Wolf Trax Boron DDP helps address the most critical challenges for efficient boron crop nutrition, with in-built technologies that provide value, convenience and flexibility – both to the farmer and the fertilizer blender.
A better boron boost
Too many micronutrients are over-applied and underutilised, but none more so than boron, says British plant scientist David Marks. Boron is one of the latest micronutrients to benefit from the ‘functional fertilizer’ approach developed by his company Levity Crop Science.
There is no simpler way to state it: boron is essential for healthy crops. An intrinsic part of the cell wall structure, this trace element is also vital in fruit and nut crops at flowering, pollen tube development and seed formation, for flag leaf development in cereals, and tuber bulking in potatoes.
“It’s fair to say that a great many crops around the world rely on boron for robust yields, marketable quality and overall plant health,” Dr Marks points out. “It’s not that farmers aren’t aware of the importance of boron; it’s just that many of them don’t see it as a problem, because boron’s quite deceptive once it gets into the plant.”
Crops readily absorb boron when it’s available, Dr Marks explains, after which it’s stored in leaves. “Growers are encouraged to tissue test for boron. Often the results will indicate ample boron levels, but that’s not the whole story.
“Boron’s mobility once in the plant is highly dependent on the individual crop. It can even change within the same crop according to growth stage or external environmental factors. The biggest mistake a grower or an adviser can make is in assuming boron behaves the same way, all the time.
“In avocados, for example, boron transport in the phloem relies on binding with complex sugars. But at times of stress, or when there’s a need to conserve energy for flowering and fruit development, complex sugar production is turned off because it’s carbon – i.e. energy – intensive.”
In these circumstances, despite adequate levels, boron often won’t reach the parts of the plant where it’s most needed. This either encourages over-application, either in quantity or frequency – which can be risky, given boron’s fine line between deficiency and toxicity – or no application at all because previous usage has appeared ineffective, notes Dr Marks.
Levity’s expertise is in functional, or ‘smart’ fertilizers. Designed to improve not just yields and quality or, in the case of soft fruit, shelf life and brix, its products are designed and formulated to ‘hijack’ existing biochemical pathways within the plant. Nutrients such as calcium, molybdenum and another recent new development, silicon, are notoriously difficult to manage in many crops – something that Dr Marks aims to resolve.
“Growers are encouraged to tissue test for boron. Often the results will indicate ample boron levels, but that’s not the whole story.
“There’s deep farmer frustration out there,” acknowledges Dr Marks, “that crops often don’t respond to these very simple trace elements and micronutrients, especially when they are so influential in determining overall and marketable yields.
“But with an understanding of exactly where the limiting factor lies, and how it manifests itself, we can design a product that gets the plant to do the heavy lifting, by making use of existing pathways.
“Take our calcium delivery product Albina, which contains proprietary LoCal technology. It improves marketable quality and shelf life in top and soft fruit. To make that work, we created our own calcium transport stimulant that emulates the plant hormone auxin – which is crucial in calcium transport.”
Damu, Levity’s boron product, takes a similar approach. Dr Marks and his team formulated a low-rate product that would avoid any phytotoxic effects, while adding a specially developed stimulant that triggers the plant to use and direct the boron where it’s needed.
“In potatoes, for example, the best timing for Damu is during periods of excess vegetative growth, when it can ‘train’ the plant to focus on root and tuber growth instead. Meanwhile the low rate allows frequent applications to keep levels constant and replenished – allowing small amounts to be applied but ensuring highly efficient use of those applications with very little wastage.”
Already enjoying success with some of Britain’s leading potato producers, Damu is also finding favour with farmers in countries and crops beyond Levity’s British base. “Peppers, tomatoes, avocados, citrus – these are all crops in which good, well-timed use of boron can deliver good fruit set and size,” Dr Marks explains.
“What’s more, we’re doing all of this without harsh chemicals, thanks to identifying and working with the natural processes already present in the plant. It’s an aspect that resonates with more and more growers, whether through pressure from buyers or their own commitment to changing the way they farm.”